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Parametric Effects of Mechanical Alloying on Carbon Nanofiber Catalyst Production in the Ni-Cu System.

Faculty Author(s): Atwater, Mark A.
Student Author(s): Guevara,Laura;Welsh, Roger
Department: AEST
Publication: Metals (2075-4701)
Year: 2018
Abstract: Mechanical alloying (MA) has been and continues to be thoroughly examined for creating structural materials, but the production of catalysts is relatively rare. This is especially true for catalysts used in the production of carbon nanofibers (CNFs), a versatile material for applications such as energy storage, catalyst support, advanced composites and others. The application of MA to create CNFs presents a valuable tool in reducing their cost and complexity, and thereby may increase their commercial potential. In this study, the effects of milling duration on CNF deposition are studied by the complementary methods of X-ray diffraction, compositional mapping, electron microscopy, particle size analysis and surface area analysis. These were used to determine microstructural and macroscale evolution of the catalyst powder and its effects on the kinetics and characteristics of carbon deposition using Ni and Ni 30 at % Cu. The results have important implications for low cost catalyst production and provide general guidance on the development of catalytic materials in miscible systems. [ABSTRACT FROM AUTHOR] Copyright of Metals (2075-4701) is the property of MDPI and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Link: Parametric Effects of Mechanical Alloying on Carbon Nanofiber Catalyst Production in the Ni-Cu System.

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